Efficient electrochemical hydrogen evolution activity of nanostructured Ag3PO4/MoS2 heterogeneous composite catalyst.

Hydrogen (H2) generation by electrochemical water splitting is a key technique for sustainable energy applications. Two-dimensional (2D) transition-metal dichalcogenide (MoS2) and silver phosphate (Ag3PO4) possess excellent electrochemical hydrogen evolution reaction (HER) properties when they are combined together as a composite rather than individuals. Reports examining the HER activity by using Ag3PO4, especially, in combination with the 2D layered MoS2 are limited in literature. The weight fraction of MoS2 in Ag3PO4 is optimized for 1, 3, and 5 wt%. The Ag3PO4/1 wt % MoS2 combination exhibits enhanced HER activity with least overpotential of 235 mV among the other samples in the acidic medium. The synergistic effect of optimal nano-scale 2D layered MoS2 structure and Ag3PO4 is essential for creating higher electrochemical active surface area of 217 mF/cm2, and hence this leads to faster reaction kinetics in the HER. This work suggests the advantages of Ag3PO4/1 wt % MoS2 heterogeneous composite catalyst for electrochemical analysis and HER indicating lower resistivity and low Tafel slope value (179 mV/dec) among the prepared catalysts making it a promising candidate for its use in practical energy applications.

A review on biofiltration techniques: recent advancements in the removal of volatile organic compounds and heavy metals in the treatment of polluted water.

Good quality of water determines the healthy life of living beings on this earth. The cleanliness of water was interrupted by the pollutants emerging out of several human activities. Industrialization, urbanization, heavy population, and improper disposal of wastes are found to be the major reasons for the contamination of water. Globally, the inclusion of volatile organic compounds (VOCs) and heavy metals released by manufacturing industries, pharmaceuticals, and petrochemical processes have created environmental issues. The toxic nature of these pollutants has led researchers, scientists, and industries to exhibit concern toward the complete eradication of them. In this scenario, the development of wastewater treatment methodologies at low cost and in an eco-friendly way had gained importance at the international level. Recently, bio-based technologies were considered for environmental remedies. Biofiltration-based works have shown a significant result for the removal of volatile organic compounds and heavy metals in the treatment of wastewater. This was done with several biological sources such as bacteria, fungi, algae, plants, yeasts, etc. The biofiltration technique is cost-effective, simple, biocompatible, sustainable, and eco-friendly compared to conventional techniques. This review article provides deep insight into biofiltration technologies engaged in the removal of volatile organic compounds and heavy metals in the wastewater treatment process.

Hybrid metal organic frameworks as an Exotic material for the photocatalytic degradation of pollutants present in wastewater: A review.

In this world, water is considered as the Elixir for all living creatures. Human life rolls with water, and every activity depends upon water. Worldwide water resources are being contaminated due to the elevation in the population count, industrialization and urbanization. Ejection of chemicals by industries and domestic sewages remains the major reason in the destruction of natural water resources. Contaminated water with harmful microbes, chemical dyes, pesticides, and carcinogens are the root cause of many diseases and deaths of living species. In this scenario, researchers engaged in producing ultra components to remove the contaminants. Metal organic frameworks (MOF) are the desired combination of organic and inorganic materials to achieve the required target. MOFs possess unique characteristics like tunable internal structure, porosity, crystallinity and high surface area which enable them for energy and environmental application. For the past years, MOFs are concentrated more as a photocatalyst in the treatment of polluted water. These research studies discuss the improvement of photocatalytic performance of MOF by the incorporation of metals, metal coupled with nanoparticles like polymers, graphene, etc., into it to achieve the enhanced photocatalytic activity by scavenging entire chemicals and harmful microbes to retain the quality of water. The target of this review article is to focus on the state of the art research work on MOFs in photocatalytic water treatment technique.

CuO-ZnO-PANI a lethal p-n-p combination in degradation of 4-chlorophenol under visible light.

Recent interest and responsibility to retain the water resources rose among people. Scientists have been engaged to develop the mechanism that involves the freely available sunlight - a sustainable resource - to remove the pollutants from water to make it again suitable for life. Ample research was reported in the removal of dye pollutants present in water. For this they have utilized p type and n type semiconductors or combination of both (p-n type) under the excitation of a wide range of electromagnetic band energy. Most of the interest lies in emerging out of the mechanism with hybrid semiconductors to remove the previously reported flaws. Toward this regard, this manuscript aims to develop unique material using the underlying p-n-p model for harnessing visible light in catalysis. Initially, p-n structure was developed with copper oxide (p-type) and zinc oxide (n-type), then polyaniline (p-type) conjugated at different concentrations (0.5 M, 0.7 M & 1.0 M), to yield p-n-p models, using precipitation followed by sonication techniques. Detailed physicochemical investigations were conducted on the resultant p-n-p material to elucidate its characteristics. Furthermore, the mechanism was advocated for the best photocatalytic activity under visible light excitation for the degradation of 4-chlorophenol and compared with the performance of a standard p-n (CuO/ZnO) combination.

Visible light driven exotic p (CuO) - n (TiO2) heterojunction for the photodegradation of 4-chlorophenol and antibacterial activity.

The treatment of industrial waste and harmful bacteria is an important topic due to the release of toxins from the industrial pollutants that damage the water resources. These harmful sources frighten the life of every organism which was later developed as the carcinogenic and mutagenic agents. Therefore, the current study focuses on the breakdown or degradation of 4-chlorophenol and the antibacterial activity against Escherichia coli (E. coli). As a well-known catalyst, pure titanium-di-oxide (TiO2) had not shown the photocatalytic activity in the visible light region. Hence, band position of TiO2 need to be shifted to bring out the absorption in the visible light region. For this purpose, the n-type TiO2 nanocrystalline material's band gap got varied by adding different ratios of p-type CuO. The result had appeared in the formation of p (CuO) - n (TiO2) junction synthesized from sol-gel followed by chemical precipitation methods. The optical band gap value was determined by Kubelka-Munk (K-M) plot through UV-Vis diffusive reflectance spectroscopy (DRS). Further, the comprehensive mechanism and the results of photocatalytic and antibacterial activities were discussed in detail. These investigations are made for tuning the TiO2 catalyst towards improving or eliminating the existing various environmental damages.

The war using microbes: A sustainable approach for wastewater management.

Anthropogenic activities and population growth have resulted in a reduced availability of drinking water. To ensure consistency in the existence of drinking water, it is inevitable to establish wastewater treatment plants (WWTPs). 70% of India's rural population was found to be without WWTP, waste disposal, and good sanitation. Wastewater has emerged from kitchens, washrooms, etc., with industry activities. This scenario caused severe damage to water resources, leading to degradation of water quality and pathogenic insects. Thus, it is a need of an hour to prompt for better WWTPs for both rural and urban areas. Many parts of the world have started to face severe water shortages in recent years, and wastewater reuse methods need to be updated. Clean water supply is not enough to satisfy the needs of the planet as a whole, and the majority of freshwater in the polar regions takes the form of ice and snow. The increasing population requires clean water for drinks, hygiene, irrigation, and various other applications. Lack of water and contamination of water result from human activities. 90% of wastewater is released to water systems without treatment in developing countries. Studies show that about 730 megatons of waste are annually discharged into water from sewages and other effluents. The sustenance of water resources, applying wastewater treatment technologies, and calling down the percentage of potable water has to be strictly guided by mankind. This review compares the treatment of domestic sewage to its working conditions, energy efficiency, etc. In this review, several treatment methods with different mechanisms involved in waste treatment, industrial effluents, recovery/recycling were discussed. The feasibility of bioaugmentation should eventually be tested through data from field implementation as an important technological challenge, and this analysis identifies many promising areas to be explored in the future.

Metal/metal oxide nanocomposites for bactericidal effect: A review.

Many microbial species causing infectious disease all over the world became a social burden and creating threat among community. These microbes possess long lifetime, enhancing mortality and morbidity rate in affected organisms. In this condition, the treatment was ineffective and more chances of spreading of infection into other organisms. Hence, it is necessary to initiate infection control efforts and prevention activities against multidrug resistant microbes, to reduce the death rate of people. Seriously concerning towards this problem progress was shown in developing significant drugs with least side effects. Emergence of nanoparticles and its novelty showed effective role in targeting and destructing microbes well. Further, many research works have shown nanocomposites developed from nanoparticles coupled with other nanoparticles, polymers, carbon material acted as an exotic substance against microbes causing severe loss. However, metal and metal oxide nanocomposites have gained interest due to its small size and enhancing the surface contact with bacteria, producing damage to it. The bactericidal mechanism of metal and metal oxide nanocomposites involve in the production of reactive oxygen species which includes superoxide radical anions, hydrogen peroxide anions and hydrogen peroxide which interact with the cell wall of bacteria causing damage to the cell membrane in turn inhibiting the further growth of cell with leakage of internal cellular components, leading to death of bacteria. This review provides the detailed view on antibacterial activity of metal and metal oxide nanocomposite which possessed novelty due to its physiochemical changes.